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Kato, Chiaki; Sato, Tomonori; Nakano, Junichi; Ueno, Fumiyoshi; Yamagishi, Isao; Yamamoto, Masahiro
Nihon Genshiryoku Gakkai Wabun Rombunshi, 14(3), p.181 - 188, 2015/09
In relation to the consideration for long-term storage of spent Cs adsorption vessels containing zeolites in the Fukushima Daiichi Nuclear Power Station, corrosion of the vessel material in the spent Cs adsorption vessel is one of important issues. We performed electrochemical tests of stainless steel (SUS 316L) in the zeolites containing artificial seawater under -ray irradiation. The spontaneous potential () and critical pitting potential (), of SUS 316L were measured to understand the corrosion resistance of the stainless steel in this study. The rest potential of the stainless steel increased with increasing time after -ray irradiation. The , defined as the steady rest potential, increased with increasing dose rate, while increasing was suppressed by contact with the zeolites. Concentration of HO in bulk water increased with increasing dose rate. The concentration increasing was suppressed by contact with the zeolites due to decomposition of HO. There was good relationship between and the concentration of HO. The of SUS 316L contacted with the zeolites decreased with increasing Cl ion concentration and is slightly smaller than the in the bulk water. The contact with the zeolites causes the suppressant of increasing under the irradiation. The contact with the zeolite can reduce probability in the localized corrosion for SUS 316L.
Kato, Chiaki; Sato, Tomonori; Ueno, Fumiyoshi; Yamagishi, Isao; Yamamoto, Masahiro
Zairyo To Kankyo 2015 Koenshu (CD-ROM), p.83 - 86, 2015/05
In relation to the consideration for long-term storage of spent Cs adsorption vessels containing zeolites in the Fukushima Daiichi Nuclear Power Station, corrosion of the vessel material in the spent Cs adsorption vessel is one of important issues. We performed electrochemical tests of stainless steel (SUS 316L) in the zeolites containing artificial seawater under gamma-ray irradiation. The spontaneous potential (ESP) and critical pitting potential (VC), of SUS316L were measured to understand the corrosion resistance of the stainless steel in this study. The rest potential of the stainless steel increased with increasing time after gamma-ray irradiation. The ESP, defined as the steady rest potential, increased with increasing dose rate, while increasing ESP was suppressed by contact with the zeolites. Concentration of HO in bulk water increased with increasing dose rate. The concentration increasing was suppressed by contact with the zeolites due to decomposition of HO. There was good relationship between ESP and the concentration of HO. The VC of SUS316L contacted with the zeolites decreased with increasing Cl ion concentration and is slightly smaller than the VC in the bulk water. The contact with the zeolites causes the suppressant of increasing ESP under the irradiation. The contact with the zeolites can reduce probability in the localized corrosion for SUS316L.
Sato, Hiroyuki; Terada, Atsuhiko; Kato, Chiaki; Yamagishi, Isao; Ikeda, Akira*; Okita, Takeshi*
no journal, ,
As a part of consideration for long-term storage of a spent zeolite adsorption vessel in the Fukushima No.1 nuclear power plant, experiment flashing salt component (5,000 ppm in chloride ion) in vessel was carried out using actual sized model of SARRY adsorption vessel.
Sato, Hiroyuki; Kimura, Shigeru; Yamagishi, Isao; Ikeda, Akira*; Okita, Takeshi*
no journal, ,
As a part of consideration for long-term storage of a spent zeolite adsorption vessel in the Fukushima Daiichi Nuclear Power Plant, experiment of non-radioactive Cesium adsorbed distribution in vessel was carried out to estimate inner environment (radiation and decay heat by radioactive Cesium) effected to corrosion in SARRY, using actual sized model of SARRY adsorption vessel.